Geochemical behavior of rare earth elements in hydrothermally altered rocks of the Kuroko mining area,Japan     

N. Shikazono  Y. Ogawa  M. Utada  D. Ishiyama  T. Mizuta  N. Ishikawa  Y. Kubota 《Journal of Geochemical Exploration》2008

In this study we analyzed the chemical composition of hydrothermally altered dacite and basalt from the Kuroko mining area, northeastern Honshu, Japan, by REE (rare earth element). Features of rare earth element analyses include: (1) altered footwall dacite exhibits a negative Eu anomaly compared with fresh dacite, suggesting preferential removal of Eu²⁺ from the altered dacite via hydrothermal solutions, (2) altered hangingwall dacite and basalt and dacite and basalt adjacent to ore deposits exhibit positive Eu anomalies compared with fresh dacite and basalt, suggesting addition of Eu²⁺ from hydrothermal solutions, (3) LREE ratio (∑LREE/∑REE) from altered dacite of chlorite–sericite zone and K-feldspar zone show a negative relationship with δ¹⁸O, and La/Sm ratios show a positive correlation with the K₂O index. These trends indicate the addition of light rare earth elements such as La to the altered dacite from hydrothermal solution and/or leaching of heavy rare earth elements such as Sm and Yb, (4) Principal component analysis (PCA) indicates that light rare earth elements enrichment is related to the formation of sericite zone near the Kuroko deposits but not to the formations of chlorite and K-feldspar zones, and (5) The correlations among REE features (LREE ratio, MREE ratio, HREE ratio, Eu/Eu?), δ¹⁸O and K₂O index are not found for montmorillonite zone, mixed layer clay mineral zone and mordenite zone. Therefore, it is inferred that sericite, chlorite and K-feldspar alterations are related to the Kuroko and vein-type mineralization, but montmorillonite and mordenite alterations are not related to the mineralizations, and probably they formed at the post-mineralization stage.  相似文献   

Experimental Investigation of the Upper Thermal Stability of Mg-rich Actinolite; Implications for Kiruna-Type Iron Deposits   总被引：2，自引：0，他引：2  

Lledo  Haroldo L.; Jenkins  David M. 《Journal of Petrology》2008,49(2):225-238

The occurrence of actinolite in magnetite deposits of possiblemagmatic origin has prompted an experimental investigation ofthe upper thermal stability of Mg-rich actinolite to determinehow the stability of actinolite changes with increasing Fe content.Experiments were carried out primarily on the compositionalre-equilibration of natural tremolite [molar Fe/(Fe + Mg) =Fe-number = 0·014] in the presence of synthetic clinopyroxene(Ca_0·80Fe_0·67Mg_0·54Si_2·00O₆), syntheticpigeonite/orthopyroxene (Ca_0·08Fe_1·19Mg_0·70Si_2·02O₆),quartz, and water to a more Fe-rich actinolite over the rangeof 600–880°C, 1 and 4 kbar, at the Ni–NiO oxygenbuffer, for durations of 1–2 weeks. The bulk compositionof the mineral mixture is close to actinolite with Fe-number= 0·5. These experiments constitute a half-reversal ofthe amphibole composition, which, when approached from a Mg-richstarting composition, provides information on the minimum Fecontent of actinolite at a given temperature. Compositionalchanges were monitored by electron microprobe analysis of amphibolerim compositions and/or overgrowths on the original tremolite.At 4 kbar and 880–800°C, tremolite shows strong re-equilibrationwith overgrowths of an Fe-rich but low-Ca (1·7 > Ca> 1·4) actinolite; Fe-rich cummingtonite (Ca <0·7)begins to nucleate at 860°C. At 800–700°C, tremoliteshows weak compositional re-equilibration but strong nucleationof Fe-rich cummingtonite. Similar results were observed at 1kbar, with tremolite showing strong re-equilibration to low-Caactinolite at 790–600°C with cummingtonite nucleationat 800°C and below. The wide variation in Ca contents ofthe re-equilibrated amphiboles was unexpected. Additional univariantreversal experiments were carried out on the thermal decompositionof a natural actinolite (Fe-number = 0·22) from PleitoMelón, Chile, indicating the breakdown of actinoliteto clinopyroxene, orthopyroxene, quartz, and water at 780°Cand 1 kbar, and 850°C and 4 kbar. Considering only amphiboleswith Ca >1·7 a.p.f.u., the thermal stability of actinoliteis observed to decrease in a linear manner over the P–Trange investigated with a dT/dFe-number slope of –372°C/Fe-numberat 1 kbar and –546°C/Fe-number at 4 kbar. The highthermal stabilities (750–900°C) of actinolites withFe-numbers in the range of 0–0·4 overlap with therange of water-saturated melting for a typical andesite or tonalite.These conditions also overlap the field of experimental Fe–P-richmelt formation, suggesting that actinolite may have an igneousorigin in Kiruna-type ore deposits. KEY WORDS: actinolite; mineral stability; Kiruna deposits, thermodynamic values; cummingonite  相似文献   

Time relationships between volcanism–plutonism–alteration–mineralization in Cu-stratabound ore deposits from the Michilla mining district,northern Chile: a <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar geochronological approach     

Verónica Oliveros  Dania Tristá-Aguilera  Gilbert Féraud  Diego Morata  Luis Aguirre  Shoji Kojima  Fernando Ferraris 《Mineralium Deposita》2008,43(1):61-78

The Michilla mining district comprises one of the most important stratabound and breccia-style copper deposits of the Coastal Cordillera of northern Chile, hosted by the Middle Jurassic volcanic rocks of the La Negra Formation. ⁴⁰Ar/³⁹Ar analyses carried out on igneous and alteration minerals from volcanic and plutonic rocks in the district allow a chronological sequence of several magmatic and alteration events of the district to be established. The first event was the extrusion of a thick lava series of the La Negra Formation, dated at 159.9 ± 1.0 Ma (2σ) from the upper part of the series. A contemporaneous intrusion is dated at 159.6 ± 1.1 Ma, and later intrusive events are dated at 145.5 ± 2.8 and 137.4 ± 1.1 Ma, respectively. Analyzed alteration minerals such as adularia, sericite, and actinolite apparently give valid ⁴⁰Ar/³⁹Ar plateau and miniplateau ages. They indicate the occurrence of several alteration events at ca. 160–163, 154–157, 143–148, and 135–137 Ma. The first alteration event, being partly contemporaneous with volcanic and plutonic rocks, was probably produced in a high thermal gradient environment. The later events may be related either to a regional low-grade hydrothermal alteration/metamorphism process or to plutonic intrusions. The Cu mineralization of the Michilla district is robustly bracketed between 163.6 ± 1.9 and 137.4 ± 1.1 Ma, corresponding to dating of actinolite coexisting with early-stage chalcocite and a postmineralization barren dyke, respectively. More precisely, the association of small intrusives (a dated stock from the Michilla district) with Cu mineralization in the region strongly suggests that the main Michilla ore deposit is related to a magmatic/hydrothermal event that occurred between 157.4 ± 3.6 and 163.5 ± 1.9 Ma, contemporaneous or shortly after the extrusion of the volcanic sequence. This age is in agreement with the Re–Os age of 159 ± 16 Ma obtained from the mineralization itself (Tristá-Aguilera et al., Miner Depos, 41:99–105,2006).  相似文献   

Hydrothermal gold mineralization at the Hira Buddini gold mine,India: constraints on fluid evolution and fluid sources from boron isotopic compositions of tourmaline     

M. -S. Krienitz  R. B. Trumbull  A. Hellmann  J. Kolb  F. M. Meyer  M. Wiedenbeck 《Mineralium Deposita》2008,43(4):421-434

We determined the boron isotope and chemical compositions of tourmaline from the Hira Buddini gold deposit within the Archean Hutti-Maski greenstone belt in southern India to investigate the evolution of the hydrothermal system and to constrain its fluid sources. Tourmaline is a minor but widespread constituent in the inner and distal alteration zones of metabasaltic and metadacite host rocks associated with the hydrothermal gold mineralization. The Hira Buddini tourmaline belongs to the dravite–schorl series with variations in Al, Fe/(Fe+Mg), Ca, Ti, and Cr contents that can be related to their host lithology. The total range of δ¹¹B values determined is extreme, from −13.3‰ to +9.0‰, but 95% of the values are between −4 and +9‰. The boron isotope compositions of metabasalt-hosted tourmaline show a bimodal distribution with peak δ¹¹B values at about −2‰ and +6‰. The wide range and bimodal distribution of boron isotope ratios in tourmaline require an origin from at least two isotopically distinct fluid sources, which entered the hydrothermal system separately and were subsequently mixed. The estimated δ¹¹B values of the hydrothermal fluids, based on the peak tourmaline compositions and a mineralization temperature of 550°C, are around +1 and +10‰. The isotopically lighter of the two fluids is consistent with boron released by metamorphic devolatilization reactions from the greenstone lithologies, whereas the ¹¹B-rich fluid is attributed to degassing of I-type granitic magmas that intruded the greenstone sequence, providing heat and fluids to the hydrothermal system. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Controls on Holocene deep‐water sedimentation in the northern Gioia Basin,Tyrrhenian Sea     

FABIANO GAMBERI  MICHAEL MARANI 《Sedimentology》2008,55(6):1889-1903

The northern Gioia Basin of the south‐east Tyrrhenian Sea is a slope basin, ～ 20 km wide and ～ 50 km long, with a bathymetry of ≤ 1300 m, bounded by the Calabro‐Sicilian landmass and the Aeolian Island Arc. Coarse sediment is supplied from the Calabrian margin, where the shelf is very narrow to non‐existent, whereas the wider shelf on the Sicilian margin prevents supply by storing river‐fed sediments. The basin is dominated by the Gioia–Mesima canyon/channel system paralleled by a tongue‐shaped depositional lobe. Multibeam bathymetric surveys, sea floor reflectivity data and airgun seismic profiles reveal the recent evolution of the submarine system. Slope canyons and basin‐floor levéed channels formed where major rivers built deltas at the shelfless Calabrian margin and strong hyperpycnal flows predominated. The channels are a few hundred metres wide and a few tens of metres deep, with a downslope change from a straight to meandering pattern where the slope gradient decreases from 3·2% to 1·7%. The Mesima Channel has its lower segment abandoned because of avulsion and crevasse‐splay formation at an upslope bend. The adjacent Gioia Channel has had its upper segment straightened and lower segment entrenched because of erosional deepening of the Stromboli Valley into which it debouches and which acts as the local base level. Overbank features include levées, coalescent splays and ‘yazoo’ channels; their nature and surface characteristics depend upon the magnitude and sediment grain‐size of spill‐over flows. On an adjoining narrow shelf sliver of the Calabrian margin, in contrast, the coalescing plumes of sediment suspension supplied by an array of smaller coastal streams were apparently spilling over the shelf edge, scouring a funnel‐shaped bypass depression with chutes and forming an elongate, non‐channellized depositional lobe at the slope base. The study demonstrates the impact of sediment source type, shelf width, basin‐floor gradient and base‐level change on the style of deep‐water sedimentation.  相似文献   

Deep‐water foreland basin deposits of the Cerro Toro Formation,Magallanes basin,Chile: architectural elements of a sinuous basin axial channel belt     

STEPHEN M. HUBBARD  BRIAN W. ROMANS  STEPHAN A. GRAHAM 《Sedimentology》2008,55(5):1333-1359

Coarse‐grained deep‐water strata of the Cerro Toro Formation in the Cordillera Manuel Señoret, southern Chile, represent the deposits of a major channel belt (4 to 8 km wide by >100 km long) that occupied the foredeep of the Magallanes basin during the Late Cretaceous. Channel belt deposits comprise a ca 400 m thick conglomeratic interval (informally named the ‘Lago Sofia Member’) encased in bathyal fine‐grained units. Facies of the Lago Sofia Member include sandy matrix conglomerate (that show evidence of traction‐dominated deposition and sedimentation from turbulent gravity flows), muddy matrix conglomerate (graded units interpreted as coarse‐grained slurry‐flow deposits) and massive sandstone beds (high‐density turbidity current deposits). Interbedded sandstone and mudstone intervals are present locally, interpreted as inner levée deposits. The channel belt was characterized by a low sinuousity planform architecture, as inferred from outcrop mapping and extensive palaeocurrent measurements. Laterally adjacent to the Lago Sofia Member are interbedded mudstone and sandstone facies derived from gravity flows that spilled over the channel belt margin. A levée interpretation for these fine‐grained units is based on several observations, which include: (i) palaeocurrent measurements that indicate flows diverged (50° to 100°) once they spilled over the confining channel margin; (ii) sandstone beds progressively thin, away from the channel belt margin; (iii) evidence that the eroded channel base was not very well indurated, including a stepped margin and injection of coarse‐grained channel material into surrounding fine‐grained units; and (iv) the presence of sedimentary features common to levées, including slumped units inferring depositional slopes dipping away from the channel margin, lenticular sandstone beds thinning distally from the channel margin, soft sediment deformation and climbing ripples. The tectonic setting and foredeep architecture influenced deposition in the axial channel belt. A significant downstream constriction of the channel belt is reflected by a transition from more tabular units to an internal architecture dominated by lenticular beds associated with a substantially increased degree of scour. Differential propagation of the fold‐thrust belt from the west is speculated to have had a major control on basin, and subsequently channel, width. The confining influence of the basin slopes that paralleled the channel belt, as well as the likelihood that numerous conduits fed into the basin along the length of the active fold‐thrust belt to the west, suggest that proximal–distal relationships observed from large channels in passive margin settings are not necessarily applicable to axial channels in elongate basins.  相似文献   

Role of basement in epithermal deposits: The Kushikino and Hishikari gold deposits, southwestern Japan     

Yuichi Morishita  Takanori Nakano 《Ore Geology Reviews》2008,34(4):597-609

The magma–ore deposit relationship of most low-sulfidation epithermal ore deposits is still unclear, partly because many stable isotopic studies of such deposits have indicated the predominance of meteoric waters within hydrothermal fluids. However, it is certainly true that hydrothermal systems are ultimately driven by magmatic intrusions, and epithermal gold deposits might therefore be produced by magmatic activity even in deposits having has no obvious links to a magma. We re-examine the genesis of two typical low-sulfidation epithermal gold deposits, the Kushikino and Hishikari deposits, using structural simulations and isotope data.Many epithermal gold deposits including the Kushikino and Hishikari deposits have been discovered in Kyushu, southwestern Japan. The Kushikino deposit comprises fissure-filling veins within Neogene andesitic volcanics that overlie unconformably Cretaceous sedimentary basement. The veins consist of gold- and silver-bearing quartz and calcite with minor amounts of adularia, sericite and sulfides. Although carbon and oxygen isotopic data for the veins indicate a meteoric origin of the ore fluid, finite element simulations suggest that the vein system might have formed in direct response to magma intrusion. In particular, geophysical data suggest that intruding magma has uplifted the basement rocks, thereby producing fractures and veins and a positive Bouguer anomaly, and providing the heat necessary to drive an ore-forming hydrothermal system.The second component of this study has been to investigate the nature and evolution of the Kushikino and Hishikari epithermal systems. Isotope data document the geochemical evolution of the hydrothermal fluids. We conclude that the existence of sedimentary basement rocks at depth might have affected the strontium and carbon isotopic ratios of the Kushikino and Hishikari ore fluids. The ⁸⁷Sr/⁸⁶Sr ratios and δ¹³C–δ¹⁸O trend reveal that major ore veins in the Hishikari deposit can be distinguished from shallow barren veins. It was suggested isotopically that fluids responsible for the barren veins in nearby shallow and barren circulation systems were only controlled by the shallow host rocks. Such multi-isotope systematics provide a powerful tool with which to determine the center of hydrothermal activity and thereby document the evolution of hydrothermal fluids.  相似文献   

Emerald deposits and occurrences: A review   总被引：3，自引：0，他引：3  

L.A. Groat  G. Giuliani  D.D. Marshall  D. Turner 《Ore Geology Reviews》2008,34(1-2):87

Emerald, the green gem variety of beryl, is the third most valuable gemstone (after diamond and ruby). Although it is difficult to obtain accurate statistics, Colombia supplies most (an estimated 60%, worth more than $500,000,000 per year) of the world's emeralds. However there is speculation that the emerald mines in Colombia are becoming depleted. Brazil currently accounts for approximately 10% of world emerald production. Emeralds have also been mined in Afghanistan, Australia, Austria, Bulgaria, China, India, Madagascar, Namibia, Nigeria, Pakistan, South Africa, Spain, Tanzania, the United States, and Zimbabwe.Because it is difficult to obtain accurate analyses of beryllium, most published analyses of beryl are renormalized on the basis of 18 oxygen and 3 Be atoms per formula unit. The color of emerald is due to trace amounts of chromium and/or vanadium replacing aluminum at the Y site; in most cases the Cr content is much greater than that of V. To achieve charge balance, the substitution of divalent cations at the Y site is coupled with the substitution of a monovalent cation for a vacancy at a channel site.Beryl is relatively rare because there is very little Be in the upper continental crust. Unusual geologic and geochemical conditions are required for Be and Cr and/or V to meet. In the classic model, Be-bearing pegmatites interact with Cr-bearing ultramafic or mafic rocks. However in the Colombian deposits there is no evidence of magmatic activity and it has been demonstrated that circulation processes within the host black shales were sufficient to form emerald. In addition, researchers are recognizing that regional metamorphism and tectonometamorphic processes such as shear zone formation may play a significant role in certain emerald deposits.A number of genetic classification schemes have been proposed for emerald deposits. Most are ambiguous when it comes to understanding the mechanisms and conditions that lead to the formation of an emerald deposit. Studies of individual emerald deposits show that in most cases a combination of mechanisms (magmatic, hydrothermal, and metamorphic) were needed to bring Be into contact with the chromophores. This suggests the need for a more flexible classification scheme based on mode of formation. Stable isotopes can be used to estimate the contribution of each mechanism in the formation of a particular deposit. Such estimates could perhaps be more precisely defined using trace element data, which should reflect the mode of formation.Emerald may be identified in the field by color, hardness, and form. It will tend to show up in stream sediment samples but because its specific gravity is relatively low, it will not concentrate in the heavy mineral fraction. In Colombia, structural geology, the sodium content of stream sediment samples, and the lithium, sodium, and lead contents of soil samples have all been used to find emerald occurrences. Exploration for gem beryl could result in the discovery of new occurrences of non-gem beryl or other Be minerals that could become new sources of Be and Be oxide.Future efforts should go towards creating a comprehensive data base of emerald compositions (including trace elements), determination of the role of metamorphism in the formation of some emerald deposits, improved classification schemes, and more effective exploration guidelines.  相似文献   

北祁连黑矿型和塞浦路斯型硫化物矿床容矿火山岩的物质来源与形成环境   总被引：2，自引：0，他引：2       下载免费PDF全文

张兰英  曲晓明  辛洪波 《矿床地质》2008,27(3)

文章以白银厂石英角斑岩和石居里富钠玄武岩为代表,对产于北祁连造山带的"黑矿型"和"塞浦路斯型"铜多金属块状硫化物矿床的容矿火山岩做了系统的常量元素、微量元素、稀土元素及锶、钕、铅同位素分析。结果表明,这2种火山岩均表现出俯冲带岩浆作用的特征。所不同的是,白银厂"黑矿型"块状硫化物矿床容矿火山岩形成于活动大陆边缘的陆缘弧环境;石居里"塞浦路斯型"硫化物铜矿床形成于大洋板块内部的洋生弧环境。与各自的形成环境相对应,白银厂的石英角斑岩来源于原生地幔在俯冲板片流体参与下的部分熔融,岩浆在上升侵位过程中有部分大陆地壳物质混入。石居里的富钠玄武岩同样也是产生于原生地幔在板片流体作用下的部分熔融,但没有遭受陆壳物质混染。  相似文献   

长江口的台风浪及其对崇明东滩的冲淤作用   总被引：1，自引：0，他引：1  

茅志昌 《海洋学研究》1993,11(4):8-16

本文分析了多年的台风和波浪资料得到如下的结果:对崇明东滩有较大影响的台风路径主要有两类:即在浙江中部至长江口登陆的台风和在长江口外侧海域转向北上的台风;佘山岛海洋站百年一遇的最大波高为5.6m;台风期间偏北、东北、东南的强风向均能引起长江口较大的增水现象。 本文还以8310号台风为例,阐明了台风前后的冲淤变化及台风浪塑造的滩地地貌形态。指出东旺沙和北八效高潮滩冲淤甚微,中低潮滩冲刷严重,奚东沙高潮滩冲刷严重,中低潮滩呈微淤状态。波浪对东滩塑造的主要地貌形态有冲刷坑和浪蚀泥坎。  相似文献